柴油机SCR尿素喷射方式研究

Research on SCR Urea Injection Method of Diesel Engine

  • 摘要: 鉴于柴油机选择性催化还原系统尿素喷射特性与氮氧(NO<sub<<i<x</i<</sub<)转化效率密切相关,本文搭建SCR系统小样试验台,NO和NH<sub<3</sub<作为主要试验用气,研究了不同氨氮比和不同温度条件下V<sub<2</sub<O<sub<5</sub<-WO<sub<3</sub</TiO<sub<2</sub<催化剂的氨存储、氨泄漏以及NO<sub<<i<x</i<</sub<转化效率的影响.结果表明:氨氮比越大,氨存储量的建立时间越短,NO<sub<<i<x</i<</sub<转化效率的提升就越快;氨氮比为0.22时,15 s内NO<sub<<i<x</i<</sub<转化效率从0增大到4.3%;当氨氮比为0.30时,15 s内NO<sub<<i<x</i<</sub<转化效率从0增大到8.7%;随着氨氮比的增大氨泄漏会提前出现;氨氮比先大后小的喷射方法有利于改善NO<sub<<i<x</i<</sub<转化效率.采用氨氮比先大后小的喷射方法,进行ETC标准循环测试,NO<sub<<i<x</i<</sub<比排放从8.26 g/(kW·h)减少到1.91 g/(kW·h),NH<sub<3</sub<泄漏均值为5×10<sup<-6</sup<,峰值为18×10<sup<-6</sup<,满足国V排放法规要求.

     

    Abstract: The characteristics of urea injection and NO<sub<<i<x</i<</sub< conversion efficiency are closely related.A SCR test bench was built based on V<sub<2</sub<O<sub<5</sub<-WO<sub<3</sub</TiO<sub<2</sub< catalyst,and NO,NH<sub<3</sub< and O<sub<2</sub< feed streams were dosed by mass flow controllers.The effect of normalized stoichiometric ratio (NSR) and catalyst temperature on ammonia storage,ammonia slip and NO<sub<<i<x</i<</sub< conversion efficiency was studied.The results show that the influence of NSR and temperature on ammonia storage,ammonia slip and NO<sub<<i<x</i<</sub< conversion efficiency is obvious.The time of ammonia storage will be shorten with the increase of NSR,then the improving speed of NO<sub<<i<x</i<</sub< conversion efficiency is high.The NSR fix 2.2,the NO<sub<<i<x</i<</sub< reduction efficiency increase from 0 to 4.3% within 15 s,and the NO<sub<<i<x</i<</sub< reduction efficiency increase from 0 to 8.7% within 15 s when NSR set 3.0.The time of ammonia slip and ammonia storage are closely related,the time of ammonia slip will be shorten with the increase of NSR.The method of NSR from larger to the smaller can increase ammonia storage rate and optimize NO<sub<<i<x</i<</sub< conversion efficiency.Using this injection method to carry out the European transient cycle(ETC) test,the brake specific emission of NO<sub<<i<x</i<</sub< reduce from 8.26 g/(kW·h) to 1.91 g/(kW·h),and the average and peak value of ammonia are 5×10<sup<-6</sup< and 18×10<sup<-6</sup<,the NO<sub<<i<x</i<</sub< can reach the National V emission regulations.

     

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