镁、铝及其铝镁合金粉尘遇水产气特性研究

Study on Gas Generation Characteristics of Magnesium, Aluminum and Aluminum-Magnesium Alloy Dusts upon Contact with Water

  • 摘要: 金属粉尘遇水反应伴随氢气释放与热量积累,易在受限空间内形成爆炸性气氛并引起事故。为探究不同因素对金属粉尘遇水产气反应的调控规律,采用HY21619型遇水放气测试仪,在20 ℃恒温条件下系统研究了加水量(10、100 mL)、粉尘质量(0.1、0.5 g)、粉尘种类(镁粉、铝粉、铝镁合金粉)及粒径(20、60、100 μm)的影响。结果表明:粉尘质量与加水量协同调控产气过程,0.5 g-10 mL条件低热容、易集热,产气量与产气速率均为最优;相同条件下产气量依次为镁粉>铝粉>铝镁合金粉,三者产气速率特征不同。实验范围内,铝镁合金粉产气总量随粒径增大先增大后减小,60 μm合金粉产气效率最高。本研究明确了各因素的调控规律,为工业湿式除尘系统实施针对性的控制提供了实验依据,对于防范金属粉尘遇湿爆炸事故具有重要理论意义。

     

    Abstract: Metal dust reacts with water with the release of hydrogen and heat accumulation, which can easily form an explosive atmosphere in confined spaces and further trigger safety accidents. To investigate the regulation law of different factors on the gas generating reaction of metal dust upon contact with water, the HY21619 type water release gas tester was used to study the effects of water addition volume (10, 100 mL), dust mass (0.1, 0.5 g), dust type (magnesium powder, aluminum powder,aluminum-magnesium alloy powder) and particle size (20, 60, 100 μm) under a constant temperature of 20 ℃. Results reveal that dust mass and water dosage jointly regulated the gas generation process. The working condition of 0.5 g–10 mL had low heat capacity and obvious heat accumulation, presenting the optimal gas yield and gas production rate. Under identical experimental conditions, gas production capacity followed the order of magnesium powder > aluminum powder > aluminum-magnesium alloy powder, and the characteristics of the gas production rates of the three were different. Within the experimental particle size range, the total gas yield of aluminum-magnesium alloy powder increased first and then decreased with the rise of particle size, and the 60 μm alloy powder possessed the best gas generation efficiency. This study provides experimental evidence for implementing targeted control measures for industrial wet dust removal systems, and has significant theoretical significance for preventing accidents involving the explosion of metal dust upon contact with moisture.

     

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